翻译 both in methodological development and mechanistic investigation. Second, recent strategies heavily rely on electro-oxidative conditions, mostly via the spirocyclic Wheland complexes and arene radicals, the corresponding electroreductive spirocyclization through Meisenheimer complexes is rarely investigated. Finally, the introduction of chiral elements, especially chiral electrocatalysts, into the electrochemical dearomative spirocyclization should be fruitful for the rapid generation of diverse chiral three-dimension spirocycles.
在方法学发展和机制研究方面。其次，最近的策略主要依赖于电氧化条件，主要通过螺环Wheland络合物和芳烃自由基，而相应的通过Meisenheimer络合物进行的电还原螺环化则很少被研究。最后，将手性元素，特别是手性电催化剂，引入到电化学去芳构化螺环化中，应该有助于快速生成多样化的手性三维螺环化合物。